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Light elements microanalysis of steel/B4C melts for nuclear power plants accident studies.


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Titre de la revue : Mikrochimica Acta Volume : 161 N° : 3-4 Pagination : 343-348 Date de publication : 01/06/2008

Type de document > *Article de revue

Mots clés > acier, analyse quantitative, carbure de bore (B4C), EPMA

Unité de recherche > IRSN/DPAM/SEREA/LEA

Auteurs > DOMINGUEZ Christina, DURIEZ Christian, JACQUEMAIN Didier, SAO JOAO Sergio

Date de publication > 01/06/2008

Résumé

Out of pile small scale tests have been carried out to study the steam oxidation of B4C-steel liquid mixtures. Microstructures and composition of the mixes were investigated by electronprobe Microanalysis (EPMA). The microprobe quantitative analysis of the light B and C elements in complex B4C-stainless steel mixtures was approached gradually starting with the simplified Fe-B system. Measurements of boron contents in Fe-B phases were achieved with an absolute error of 2 %. In addition, phase area ratio determination by BSE images analysis was coupled to quantitative analysis data to estimate the global composition of the samples. For non oxidized samples, a good correlation was obtained between this microanalysis determination and actual composition of the samples. The evolution of this global composition during the oxidation process was studied by performing successive tests with increasing oxidation duration. A preferential oxidation of boron and chromium was revealed.