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Chimie de l'iode dans les recombineurs d'hydrogène


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J.C. Sabroux* and F. Deschamps** , Congress EUROSAFE 2005 - Bruxelles 2005, november 07th-08th .

Type de document > *Congrès/colloque

Mots clés > hydrogène, terme source

Unité de recherche > IRSN/DSU/SERAC

Auteurs > SABROUX Jean-Christophe

Date de publication > 07/11/2005

Résumé

Hydrogen recombiners, recently introduced in the French nuclear reactor buildings, display high temperature (up to ca. 900°C) and several thousands square meters of a very reactive surface when operating during a severe accident scenario. Small scale analytical experiments show that cesium and cadmium iodides are unstable, and generate volatile iodine, when heated in an oven that reproduces most physico-chemical parameters of recombiner operation. Based on these results, and due to its potential with regard to the environmental source term of a severe accident, iodine chemistry in hydrogen recombiners deserves close and careful scrutiny.

* IRSN/DSU/SERAC, B.P. N°68, 91192 Gif-sur-Yvette cedex, France
** APTUS, 77 rue des Chantiers, 78000 Versailles, France